有机合成现代方法(第4版)(英文影印版)

书籍

化工书店

英 语 科学社会主义理论 自然辩证法 近代仪器分析★ 高等仪器分析实验 高等物理化学 化学动力学 应用电化学★ 量子化学 物理化学前沿讲座 催化原理★ 化学热力学 色谱分离技术 光化学 统计热力学 中药有效成分分离技术 界面化学 专业英语阅读 工业催化剂设计 电化学能源 二外、 数学、 计算机、 体育、 管理、经济、法律类 跨学科的专业课程 文献综述、开题报告。科学社会主义理论 自然辩证法 近代仪器分析 高等仪器分析实验 材料与精细化学品化学 分离化学与技术 功能材料 色谱分离技术 应用化学前沿 应用化学实验 化学信息资源与应用 组合化学 精细有机合成 稀有元素化学 催化材料化学 二外、数学、计算机、体 育、管理、经济、法律类 跨学科的专业课程 文献综述、开题报告。如以Ｍｎ２＋→Ｍｎ３＋＋ｅ－为氧化还原中介物间接电化学氧化异丁子香酚合成香兰素有机合成现代方法有机合成现代方法，阳极为ＰｂＯ２，阴极用Ｎｉ片电极。

the fourth edition of this well-known textbook discusses the key methods used in organic synthesis, showing the value and scope of these methods and how they are used in the synthesis of complex molecules。 all the text from the third edition has been revised, to produce a modem account of traditional methods and an up-to-date description of recent advancements in synthetic chemistry。 the textbook maintains a traditional and logical approach in detailing carbon--carbon bond formations,followed by a new chapter on the functionalization of alkenes and concluding with oxidation and reduction reactions。

reference style has been improved to include footnotes, allowing easy and rapid access to the primary literature。 in addition, a selection of problems has been added at the end of each chapter, with answers at the end of the book。 the book will be of significant interest to chemistry and biochemistry students at advanced undergraduate and graduate level, as well as to researchers in academia and industry who wish to familiarize themselves with modem synthetic methods。

Preface to the first edition

Preface to the fourth edition

1 Formation of carbon-carbon single bonds

1.1 Main-group chemistry

1.1.1 Alkylation of enolates and enamines

1.1.2 Conjugate addition reactions of enolates and enamines

1.1.3 The aldol reaction

1.1.4 Asymmetric methodology with enolates and enamines

1.1.5 Organolithium reagents

1.1.6 Organomagnesium reagents

1.1.7 Organozinc reagents

1.1.8 Allylic organometallics of boron, silicon and tin

1.2 Transition-metal chemistry

Problems

1.2.1 Organocopper reagents

1.2.2 Organochromium chemistry

1.2.3 Organocobalt chemistry

1.2.4 Organopalladium chemistry

2 Formation of carbon-carbon double bonds

2.1 B-Elimination reactions

2.2 Pyrolytic syn eliminations

2.3 Fragmentation reactions

2.4 Alkenes from hydrazones

2.5 Alkenes from 1,2-diols

2.6 Alkenes from alkynes

2.7 The Wittig and related reactions

2.8 Alkenes from sulfones

2.9 Alkenes using titanium or chromium reagents

2.10 Alkene metathesis reactions

Problems

3 Pericyclic reactions

3.1 The Diels-Alder cycloaddition reaction

3.1.1 The dienophile

3.1.2 The diene

3.1.3 Regiochemistry of the Diels-Alder reaction

3.1.4 Stereochemistry of the Diels-Alder reaction

3.1.5 Intramolecular Diels-Alder reactions

3.1.6 The retro Diels-Alder reaction

3.1.7 Asymmetric Diels-Alder reactions

3.2 [2+2] Cycloaddition reactions

3.3 Cycloaddition reactions with allyl cations and allyl anions

3.4 1,3-Dipolar cycloaddition reactions

3.5 The ene reaction

3.6 [3,3]-Sigmatropic rearrangements

3.6.1 The Cope rearrangement

3.6.2 The Claisen rearrangement

3.7 [2,3]-Sigmatropic rearrangements

3.8 Electrocyclic reactions

Problems

4 Radical and carbene chemistry

4.1 Radicals

4.1.1 Radical abstraction reactions

4.1.2 Radical addition reactions

4.2 Carbenes

Problems

5 Functionalization of alkenes

5.1 Hydroboration

5.1.1 Reactions of organoboranes

5.2 Epoxidation and aziridination

5.2.1 Epoxidation

5.2.2 Asymmetric epoxidation

5.2.3 Aziridination

……

6 Oxidation

7 Reduction

Answers to problems

Index