脱落酸类似物脱落酸类似物Allinger N L, Spra(7)

26. qing-qing cheng, shou-fei zhu*, yong-zhen zhang, xiu-lan xie, qi-lin zhou*, copper-catalyzed b–h bond insertion reaction: a highly efficient and enantioselective c–b bond-forming reaction with amine- and phosphine-borane adducts, j. am. chem. soc. 2013, 135, 14094–14097. (highlighted by synfacts 2013, 9, 1323).。120.ming-lei yuan, jian-hua xie*, xiao-hui yang, qi-lin zhou*,enantioselective synthesis of chiral 1,2-amino alcohols via asymmetric hydrogenation of α-amino ketones with chiral spiro iridium catalysts, synthesis 2014。

1996年 参加“中国新文人画96展”。迄今，在包括science, chem. rev., chem. soc. rev., acc. chem. res., j. am. chem. soc., angew. chem. int. ed., nat. commun.等期刊上发表sci检索论文300余篇。迄今在chem. soc. rev.、j. am. chem. soc.、adv. mater.、chem. commun.、org. lett.、chem. eur. j.、adv. synth. catal.、chemcatchem等发表文章60余篇，其中影响因子大于5的30余篇。

Sturla L, Fresia C, Guida L, Bruzzone S, Scarfì S, Fruscione F, Magnone M, Millo M, Basile G, Grozio A, Jacchetti E, Allegretti M, De Flora A and Zocchi E (2009). LANCL2 is necessary for abscisic acid binding and signaling in human granulocytes and in rat insulinoma cells. J Biol Chem 284, 28045-28057

Todoroki Y, Hirai N, Koshimizu K (1994). 8'- and 9'-Methoxyabscisic acids as antimetabolic analogs of abscisic acid. Biosci Biotech Biochem 58, 707-715

abstract:a convenient two-step homologation of both aliphatic and aromatic ketones to the corresponding carboxylic acid has been developed. first ketones were converted to epoxynitriles with the darzens reaction. second, a lewis acid mediated rearrangement of these epoxynitriles with lithium bromide was achieved to give homologated secondary alkanoic acids (as well as aryl-alkanoic) in good yields. the mechanism and the scope of the rearrangement reaction were investigated. this strategy constitutes a two-step homologation of ketones to secondary carboxylic acids.。phenylpropionic acid, cinnamic acid or the derivatives of these acids。